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You need to declare all your headers just like a normal mail but now as variable names eg
$to = 'someone@example.com
$subject = 'Your Subject'
$message = 'Hello World!'
$headers = 'From: mzito@example.com' \r\n
Then take your variables and put them in the mail() function
Not everything required in my answer may have been included because I haven't tried it yet but I'm sure it'll be of some help.