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From MSDN:
The % operator computes the remainder after dividing its first operand by its second. All numeric types have predefined remainder operators.
So in your case, the following string
a %= b;
is the same as this one:
a = a % b;
Which also applies to all operators:
a += b equals to a = a + b
a /= b equals to a = a / b
a -= b equals to a = a - b
etc.